You can get the compiler to tell you its search paths pretty easily.
$ touch /tmp/a.cxx
$ clang -std=c++11 -v /tmp/a.cxx
Apple LLVM version 7.0.2 (clang-700.1.81)
Target: x86_64-apple-darwin14.5.0
Thread model: posix
"/Library/Developer/CommandLineTools/usr/bin/clang" -cc1 -triple x86_64-apple-macosx10.10.0 -Wdeprecated-objc-isa-usage -Werror=deprecated-objc-isa-usage -emit-obj -mrelax-all -disable-free -disable-llvm-verifier -main-file-name a.cxx -mrelocation-model pic -pic-level 2 -mthread-model posix -mdisable-fp-elim -masm-verbose -munwind-tables -target-cpu core2 -target-linker-version 253.9 -v -dwarf-column-info -resource-dir /Library/Developer/CommandLineTools/usr/bin/../lib/clang/7.0.2 -stdlib=libc++ -std=c++11 -fdeprecated-macro -fdebug-compilation-dir /Volumes/Hardware IO Tools -ferror-limit 19 -fmessage-length 238 -stack-protector 1 -mstackrealign -fblocks -fobjc-runtime=macosx-10.10.0 -fencode-extended-block-signature -fcxx-exceptions -fexceptions -fmax-type-align=16 -fdiagnostics-show-option -fcolor-diagnostics -o /var/folders/3r/ypbpyb9512j8c933tp_b5whm0000gn/T/a-0ad1fb.o -x c++ /tmp/a.cxx
clang -cc1 version 7.0.2 based upon LLVM 3.7.0svn default target x86_64-apple-darwin14.5.0
ignoring nonexistent directory "/usr/include/c++/v1"
#include "..." search starts here:
#include <...> search starts here:
/Library/Developer/CommandLineTools/usr/bin/../include/c++/v1
/usr/local/include
/Library/Developer/CommandLineTools/usr/bin/../lib/clang/7.0.2/include
/Library/Developer/CommandLineTools/usr/include
/usr/include
/System/Library/Frameworks (framework directory)
/Library/Frameworks (framework directory)
End of search list.
"/Library/Developer/CommandLineTools/usr/bin/ld" -demangle -dynamic -arch x86_64 -macosx_version_min 10.10.0 -o a.out /var/folders/3r/ypbpyb9512j8c933tp_b5whm0000gn/T/a-0ad1fb.o -lSystem /Library/Developer/CommandLineTools/usr/bin/../lib/clang/7.0.2/lib/darwin/libclang_rt.osx.a
Undefined symbols for architecture x86_64:
"_main", referenced from:
implicit entry/start for main executable
ld: symbol(s) not found for architecture x86_64
clang: error: linker command failed with exit code 1 (use -v to see invocation)